Lihlahisoa
1,3-Propane sultone
Propane sultone Chemical Properties
| Sebaka se qhibilihang | 30-33 °C (hote.) |
| Ntho e belang | 180 °C/30 mmHg (hote.) |
| tekano | 1.392 g/mL ho 25 °C (hote.) |
| khatello ea mouoane | 0.001-0.48Pa ho 20-25℃ |
| index ea refractive | 1.4332 (khakanyo) |
| Fp | >230 °F |
| mocheso oa polokelo. | Boemo bo sa tsitsang, Mocheso oa Kamore |
| sebopeho | phofo |
| mmala | Bosweu kapa bo se nang mmala ho ya ho bosehla bo kganyang |
| Ho qhibiliha ha Metsi | E qhibilihang hanyane |
| FreezingPoint | 30.0 ho isa ho 33.0 ℃ |
| E hloahloa | E Mamela Mongobo |
| BRN | 109782 |
| Botsitso: | E tsitsitse, empa e na le maikutlo a mongobo.Ha e lumellane le li-oxidizing tse matla, li-acids tse matla, metheo e matla. |
| InChIKey | FSSPGSAQUIYDCN-UHFFFAOYSA-N |
| LogP | -2.86--0.28 ka 20℃ |
| Referense ea CAS DataBase | 1120-71-4(CAS DataBase Reference) |
| Referense ea Khemistri ea NIST | 1,2-Oxathiolane, 2,2-dioxide(1120-71-4) |
| IARC | 2A (Moqolo. 4, Sup 7, 71, 110) 2017 |
| EPA Substance Registry System | 1,3-Propane sultone (1120-71-4) |
Boitsebiso ba Tšireletseho
| Likhoutu tsa Kotsi | T |
| Lipolelo tsa Kotsi | 45-21/22 |
| Lipolelo tsa Tšireletseho | 53-45-99 |
| RIDADR | UN 2810 6.1/PG 3 |
| WGK Jeremane | 3 |
| RTECS | RP5425000 |
| F | 21 |
| TSCA | Ee |
| HazardClass | 6.1 |
| Sehlopha sa Packing | III |
| Khoutu ea HS | 29349990 |
| Lintlha tsa Lintho Tse Kotsi | 1120-71-4(Boitsebiso ba Lintho Tse Kotsi) |
Tšebeliso ea Propane sultone le Synthesis
| Tlhaloso | Propane sultone eo hape e tsejoang e le 1,3-propane sultone e qalile ho hlahisoa United States ka 1963. Propane sultone e teng mochesong oa kamore e le mokelikeli o se nang ’mala o monko o litšila kapa o tiileng joaloka kristale e tšoeu. |
| Lintho tsa Lik'hemik'hale | 1,3-Propane sultone ke 'mala o mosoeu oa kristale kapa mokelikeli o se nang 'mala o ka holimo ho 30°C.E ntša monko o litšila ha e ntse e qhibiliha.E qhibiliha habonolo metsing le lihlapolli tse ngata tsa tlhaho tse kang ketone, li-ester le li-hydrocarbon tse nkhang hamonate. |
| Lisebelisoa | 1,3-Propane sultone e sebelisoa e le lik'hemik'hale tse bohareng ho hlahisa sehlopha sa sulfopropyl ka limolek'hule le ho fana ka ho qhibiliha ha metsi le sebopeho sa anionic ho limolek'hule.E sebelisoa e le setsi sa lik'hemik'hale tlhahisong ea li-fungicides, likokoanyana tse bolaeang likokoanyana, li-resin tsa cation-exchange, lidae, li-accelerator tsa vulcanization, li-detergents, li-lathering agents, li-bacteriostats, le mefuta e meng ea lik'hemik'hale tse ling hape e le corrosion inhibitor bakeng sa tšepe e bonolo (e sa tsitsang). |
| Kopo | 1,3-Propanesultone ke cyclic sulfonic ester haholo-holo e sebelisetsoang ho hlahisa propane sulfonic tshebetso ka har'a sebopeho sa lintho tse phelang.E 'nile ea sebelisoa ho lokisetsa poly[2-ethynyl-N-(propylsulfonate)pyridinium betaine],novel poly(4-vinylpyridine) tshehetswa acidic ionic liquid catalyst,novel poly(4-vinylpyridine) tshehetswa acidic ionic mokelikeli catalyst. 1,3-Propanesultone e ka sebelisoa ho kopanya: A sulfonic acid functionalized acidic ionic liquid modified silica catalyst e ka sebelisoang ho hydrolysis ea selulose. Matsoai a qhibilihileng a mofuta oa Zwitterionic a nang le thepa e ikhethang ea ion conductive. Zwitterionic organofunctional silicones ka quaternization ea li-silicone tse sebetsang tsa amine. |
| Tokisetso | 1,3-propane sultone e hlahisoa khoebong ka dehydrating gamma-hydroxy-propanesulfonic acid, e lokiselitsoeng ho tloha sodium hydroxypropanesulfonate.letsoai lena la sodium le lokisoa ka ho eketsoa ha sodium bisulfite ho allyl alcohol. |
| Tlhaloso | 1,3-Propane sultone ke sultone.E sebelisoa e le lik'hemik'hale tse mahareng.Ha e chesa ho isa ho bola, e ntša mosi o chefo oa sulfur oxides.Batho ba ka 'na ba pepesetsoa masala a 1,3-propane sultone ha ba sebelisa lihlahisoa tse entsoeng ka motsoako ona.Litsela tsa mantlha tsa ho pepeseha ha motho ho 1,3-propane sultone ke ho monya le ho hema.Ho kopana le k'hemik'hale ena ho ka baka ho halefa ha bonolo mahlong le letlalo.Ho lebelletsoe ka nepo hore ke kankere ea motho. |
| Tlhaloso e Akaretsang | Propanesultone ke mokelikeli o entsoeng ka maiketsetso, o se nang 'mala kapa o soeufetse oa kristale o qhibilihang habonolo ka metsing le metsoako e mengata ea tlhaho e kang ketone, ester le li-hydrocarbon tse nkhang hamonate.Sebaka sa ho qhibiliha ke 86°F.E ntsha monko o mobe ha e qhibidiha. |
| Maikutlo a Moea le Metsi | E qhibilihang ka metsing [Hawley]. |
| Boemo ba Reactivity | 1,3-Propanesultone e arabela butle ka metsi ho fana ka 3-hydroxopropanesulfonic acid.Karabelo ena e ka potlakisoa ke asiti.E ka 'na ea arabela ka lisebelisoa tse matla tse fokotsang ho fana ka hydrogen sulfide e chefo le e tukang. |
| Kotsi | Ho ka etsahala carcinogen. |
| Kotsi ea Bophelo bo Botle | Propane sultone ke carcinogen liphoofolong tsa liteko le seo ho nahanoang hore ke kankere ea motho.Ha ho na data ea motho e fumanehang.Ke carcinogen ho likhoto ha e fanoa ka molomo, ka methapo, kapa ka ho pepesehela pelehi le kankere ea lehae ho litoeba le likhoto ha e fanoa ka tlas'a letlalo. |
| Ho chesa le ho phatloha | E sa cheng |
| Boemo ba Polokeho | E netefalitsoeng ea kankere e nang le lintlha tsa liteko tsa carcinogenic, neoplasigenic, tumorigenic, le teratogenic.Chefo ka subcutaneous route.Chefo e itekanetseng ka ho kopana le letlalo le litsela tsa intraperitoneal.Ho tlalehiloe lintlha tsa phetoho ea batho.E ameha joalo ka carcinogen ea boko ba motho.Motho ea khopisang.Ha e chesa ho bola e ntša mosi o chefo oa SOx. |
| Kgonahalo ya kgahlamelo | Kotsi e ka bang teng ho ba amehang ts'ebelisong ea k'hemik'hale ena ea lipakeng ho hlahisa sehlopha sa sulfopropyl (-CH 2 CH 2 CH 2 SO 3-) ho limolek'hule tsa lihlahisoa tse ling. |
| Lefu la kankere | 1,3-Propane sultone e lebeletsoe ka mokhoa o utloahalang hore e ka ba kankere ea motho e thehiloeng bopaking bo lekaneng ba kankere ho tsoa lithutong tsa liphoofolo tsa liteko. |
| Qetello ea Tikoloho | Litsela le Litsela le Lits'ebetso tsa Physicochemical tse Amanang Ponahalo: Mokelikeli o mosoeu oa kristale o tiileng kapa o se nang 'mala. Motsoako: o qhibiliha habonolo ka har'a li-ketone, li-ester le li-hydrocarbon tse nkhang hamonate;e sa qhibiliheng ka har'a aliphatic hydrocarbons;'me e qhibiliha ka metsing (100 gl-1). Karohano ea Boitšoaro ka Metsing, Sediment, le Mobu Haeba 1,3-propane sultone e ka theoleloa mobung, ho tla lebelloa hore e tsoe ka hydrolyze ka potlako haeba mobu o le mongobo, ho ipapisitsoe le hydrolysis e potlakileng e bonoang tharollong ea metsi.Kaha e potlakisa hydrolyzes, adsorption le volatilization ho tloha mobung o mongobo ha e lebeletsoe hore e be lits'ebetso tsa bohlokoa, leha ho se na lintlha tse mabapi le pheletso ea 1,3-propane sultone mobung e neng e le teng.Haeba e lokolloa ka metsing, ho tla lebelloa hore e be hydrolyze ka potlako.Sehlahisoa sa hydrolysis ke 3-hydroxy-1-propansulfonic acid.Kaha e phalla ka potlako, bioconcentration, volatilization, le adsorption to sediment le lintho tse tiileng tse emisitsoeng ha li lebeletsoe hore e be lits'ebetso tsa bohlokoa.Haeba e ka lokolloa sepakapakeng, e tla ba bonolo ho photooxidation ka tsela ea mouoane ka li-radicals tsa hydroxyl tse hlahisoang ke photochemically tse nang le halofo ea bophelo ea matsatsi a 8 e hakantsoeng bakeng sa ts'ebetso ena. |
| Ho tsamaisa ka sekepe | UN2811 Lintho tse chefo, lintho tse phelang, li-nos, Sehlopha sa Kotsi: 6.1;Labels: 6.1-Lisebelisuoa tse chefo, Lebitso la Setsebi le Hlokahala.UN2810 Mekelikeli e chefo, manyolo, nos, Sehlopha sa Kotsi: 6.1;Labels: 6.1-Lisebelisuoa tse chefo, Lebitso la Setsebi le Hlokahala. |
| Tlhahlobo ea chefo | Boitšoaro ba propane sultone ka guanosine le DNA ka pH 6-7.5 e fane ka N7-alkylguanosine e le sehlahisoa se seholo (> 90%).Bopaki bo ts'oanang bo bontšitse hore tse peli tsa li-adducts tse nyane e ne e le N1- le N6-alkyl derivatives, e leng karolo ea hoo e ka bang 1.6 le 0.5% ea kakaretso ea kakaretso, ka ho latellana.N7- le N1-alkylguanine le tsona li ile tsa fumanoa ho DNA li ile tsa arabela ka propane sultone. |
| Ho se lumellane | Ha e lumellane le li-oxidizers (chlorate, nitrate, peroxides, permanganate, perhlorates, chlorine, bromine, fluorine, joalo-joalo);ho kopana ho ka baka mollo kapa ho phatloha.Qoba hole le lisebelisoa tsa alkaline, metheo e matla, li-acid tse matla, li-oxoacids, li-epoxide. |
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