Potassium peroxymonosulfate

Tlhaloso e Khutšoanyane:

Lebitso la Sehlahisoa:Potassium peroxymonosulfate

Mantsoe a tšoanang:Potassium peroxymonosulfate,Active Oxygen≥4.5%;Potassium hydrogen monopersulfate;Potassium peroxymonosulfate joyce;OXONE, MONOPERSULFATE COMPOUNDOXONE, MONOPERSULFATE COMPOUNDOXONE, MONOPERSULFATE COMPOUNDOXONE, MONOPERSULFATE POxytamosulfatePossiosulfate hydrogen COMPOUNDFOUMDUMPOUNDOM; trioxidan-1-ide;PotassiumM Monopersultate coMpound;Oxone , potasiamo monopersulfate

CAS:70693-62-8

MF:HKO6S

MW:168.17

EINECS:274-778-7

Lihlopha tsa lihlahisoa:Lintho tsa tlhaho

Mol File:70693-62-8.mol

Re romelle lengolo-tsoibila

Lintlha tsa Sehlahisoa

Li-tag tsa Sehlahisoa

Potassium Peroxymonosulfate Chemical Properties

tekano	1.15
mocheso oa polokelo.	E boloke ho <= 20°C.
ho qhibiliha	250-300g / l e qhibilihang
sebopeho	tiileng
mmala	tšoeu
Matla a Khoheli a khethehileng	1.12-1.20
PH	2-3 (10g/l, H2O, 20℃)
Ho qhibiliha ha Metsi	E qhibiliha ka metsing (100 mg / ml).
E hloahloa	Hygroscopic
Meeli ea ho pepeseha	ACGIH: TWA 0.1 mg/m3
Botsitso:	E tsitsitseng.Oxidizer.Ha e lumellane le lisebelisoa tse tukang, metheo.
InChIKey	HVAHYVDBVDILBL-UHFFFAOYSA-M
LogP	-3.9 ho 25 ℃
Referense ea CAS DataBase	70693-62-8(CAS DataBase Reference)
EPA Substance Registry System	Potassium peroxymonosulfate sulfate (K5[HSO3(O2)][SO3(O2)](HSO4)2) (70693-62-8)

Potassium Peroxymonosulfate Tlhaloso ea Sehlahisoa

Potassium peroxymonosulfate, eo hape e tsejoang e le potassium monopersulfate kapa potasiamo peroxodisulfate, ke ntho e matla ea oxidizing e sebelisoang hangata lits'ebetsong tse fapaneng.

Ke phofo e tšoeu ea kristale e qhibilihang haholo metsing 'me e tsitsitse mocheso oa kamore.E 'ngoe ea litšebeliso tse atileng haholo tsa potasiamo persulfate ke sesebelisoa sa oxidizing letamong la ho sesa le kalafo ea metsi ea spa.E thusa ho tlosa litšila tse phelang, ho bolaea libaktheria, ho felisa algae le ho ntlafatsa ho hlaka ha metsi.Hangata e rekisoa tlasa mabitso a marang-rang a fapaneng ka granule kapa foromo ea letlapa.Potassium peroxymonosulfate e boetse e sebelisoa e le sebolaea-mafu le sebolaea likokoana-hloko lits'ebetsong tse fapaneng tsa indasteri joalo ka ho hloekisa metsi a litšila, makhasi le pampiri, le motsoako oa lik'hemik'hale.

Ho feta moo, e sebelisoa libakeng tsa laboratori ho hloekisa le ho bolaea likokoana-hloko lisebelisoa le bokaholimo.Ke habohlokoa ho nka mehato e nepahetseng ea tšireletso ha u sebetsana le potassium sulfate.E ka 'na ea halefisa mahlo, letlalo le tsamaiso ea ho hema, kahoo li-goggles, li-gloves le mask li buelloa.Mekhoa e nepahetseng ea ho lahla le eona e lokela ho lateloa ho thibela tšilafalo ea tikoloho.Ke habohlokoa ho hlokomela hore peroxymonosulfate ea potasiamo ha ea lokela ho ferekanngoa le potassium persulfate, e 'ngoe ea oxidizing e nang le thepa e tšoanang empa e fapane le sebopeho sa lik'hemik'hale le tšebeliso.

Boitsebiso ba Tšireletseho

Likhoutu tsa Kotsi	O,C
Lipolelo tsa Kotsi	8-22-34-42/43-37-35
Lipolelo tsa Tšireletseho	22-26-36/37/39-45
RIDADR	UN 3260 8/PG 2
WGK Jeremane	1
TSCA	Ee
Khoutu ea HS	2833 40 00
HazardClass	5.1
Sehlopha sa Packing	III
Chefo	LD50 ka molomo ho Mmutla: > 2000 mg/kg

Tšebeliso ea Potassium Peroxymonosulfate Le Synthesis

Boitšoaro	Reagent bakeng sa catalytic asymmetric Shi epoxidation Reagent bakeng sa tlhahiso ea nitro heteroaromatics ka metsing Reagent bakeng sa li-syntheses tsa benzoxazoles le benzothiazoles ho sebelisa aryl iodides ka CH functionalization le CO/S bond Reagent e sebelisetsoang bromolactonization ho asymmetric total synthesis ea (+)-Dubiusamine C Reagent bakeng sa benzofuran oxidative dearomatization cascade ho kakaretso ea motsoako oa Integrastatin B.
Lintho tsa Lik'hemik'hale	phofo e tšoeu ea kristale
Lisebelisoa	PCB tšepe holim'a phekolo ea lik'hemik'hale le phekolo ea metsi joalo-joalo.
Lisebelisoa	Oxone e sebelisoa bakeng sa halogenation ea a,b-unsaturated carbonyl metsoako le catalytic tlhahiso ea hypervalent reagents iodine bakeng sa joala oxidation.E sebelisoa bakeng sa motsoako o potlakileng, le o motle oa oxaziridines.
Tlhaloso e Akaretsang	OXONE^?, motsoako oa monopersultate ke letsoai la potasiamo le makhetlo a mararo haholo-holo le sebelisoang e le mokhoa o tsitsitseng, o bonolo ho sebetsana le oxidant e seng chefo.
Ho chesa le ho phatloha	E sa cheng
Mekhoa ea ho Hloekisa	Ena ke mofuta o tsitsitseng oa asiti ea Caro mme e lokela ho ba le >4.7% ea oksijene e sebetsang.E ka sebelisoa ho litharollo tsa EtOH/H2O le EtOH/AcOH/H2O.Haeba oksijene e sebetsang e le tlase haholo.ho molemo ho e lokisa bocha ho tloha ho 1mole ea KHSO5, 0.5mole ea KHSO4 le 0.5mole ea K2SO4.[Kennedy & Stock J Org Chem 25 1901 1960, Stephenson US Patent 2,802,722 1957.] Tokiso e potlakileng ea asiti ea Caro e entsoe ka ho hlohlelletsa phofo ea potassium persulfate (M 270.3) ka har'a leqhoa le batang la H2SO4 le leqhoa ha le eketsa leqhoa (7mL) (40-50g).E tsitsitse matsatsi a 'maloa haeba e bolokiloe e bata.E-ba hole le lintho tsa tlhaho kaha ke OXIDANT E MATLA.Tokiso e qaqileng ea Caro's acid (hypersulfuric acid, H2SO5) ka sebopeho sa crystalline m ~45o ho tloha H2O2 le chlorosulfonic acid e hlalositsoe ke Fehér ho Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 388 1963.